Solution:

Let $\angle A = \alpha,$ and scale so $AP = PQ = QB = BC = 1.$ In triangle $APQ,$ the equal sides $AP = PQ$ give $\angle AQP = \angle A = \alpha,$ so $\angle APQ = 180^\circ - 2\alpha$ and, by the law of sines, $AQ = \frac{\sin 2\alpha}{\sin \alpha} = 2\cos\alpha.$ In triangle $ABC,$ $\angle B = \angle C = 90^\circ - \frac{\alpha}{2},$ so $$AB = \frac{BC \sin C}{\sin A} = \frac{\cos(\alpha/2)}{\sin\alpha} = \frac{1}{2\sin(\alpha/2)}.$$

Since $AQ + QB = AB,$ $$2\cos\alpha + 1 = \frac{1}{2\sin(\alpha/2)} \quad\Longrightarrow\quad 4\sin\tfrac{\alpha}{2}\cos\alpha + 2\sin\tfrac{\alpha}{2} = 1.$$ By the product-to-sum identity, $4\sin\frac{\alpha}{2}\cos\alpha = 2\sin\frac{3\alpha}{2} - 2\sin\frac{\alpha}{2},$ so the equation collapses to $\sin\frac{3\alpha}{2} = \frac{1}{2}.$ Then $\alpha = 20^\circ$ or $\alpha = 100^\circ,$ but the latter makes $AQ = 2\cos\alpha$ negative, so $\alpha = 20^\circ.$

Now $\angle ACB = 80^\circ$ and $\angle APQ = 140^\circ,$ so $r = \frac{80}{140} = \frac{4}{7},$ and $\lfloor 1000r \rfloor = \left\lfloor \frac{4000}{7} \right\rfloor = 571.$