Solution:

Split the $6$ juniors into three unordered pairs. There are $\frac{6!}{2!^3 3!} = 15$ ways, and the same $15$ for the seniors. Each team is one junior-pair paired with one senior-pair, so we match the three junior-pairs to the three senior-pairs in $3! = 6$ ways. That's $15 \cdot 15 \cdot 6 = 1350$ sets of teams. Thus, B is the correct answer.